You haven't mentioned which exact version of OrCAD Capture (I guess) that you are using, check from Help>About, but I suspect that the schematic may be corrupted, try copying the schematic pages to a new design, or try moving the pages to a new schematic folder in the same design and then add the pages to the root schematic folder one at a time and try printing the PDF for one page, then two and so on to isolate the pages with the issue. If that fails, you will likely need to involve Cadence Support, either directly, or via your Cadence Channel Partner, to investigate the issue.
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